See also Marvel Super-Heroes: Secret Wars #8 for 1st time Spider-Man's black costume is mentioned as an alien costume, and. 1st time the black suit is referred to as a symbiote. Early promotional appearances of Spider-Man's Black Symbiote Costume, pre-dating first appearance in main titles are in Amazing Heroes #35, #39, Marvel Age #12 and Heroes Hotline Dec. The item "Marvel Team-Up #141 1 of the 3 first appearances of the symbiote black suit" is in sale since Tuesday, August 6, 2019. This item is in the category "Collectibles\Comics\Copper Age (1984-1991)\Superhero\Spider-Man".The seller is "comic-zone" and is located in Toronto, ON. This item can be shipped worldwide.